Thursday, October 31, 2019

Renaissance Art Categories Essay Example | Topics and Well Written Essays - 500 words

Renaissance Art Categories - Essay Example Commonly known as early renaissance art, fifteenth-century Italian Art was known for its artistic unsuitable behavior in the republic of Florence between 1417 and 1494. The majority of the art developed during this period originated from Florence due to several aspects that art from this period grasped. Italian art dominated this scene, with a variety of rivalries occurring amongst Christian leaders, regarding the arts to be depicted in religious architecture. According to Stokstad and Cothren, the rivalries amongst religious leaders over the arts also contributed o the definition of the art trends and pieces themselves. The rivalries that were experienced include contending popes, Florence and aggressive neighbors, humanitarians and devout religion followers and entertainers. 3. Sixteenth-century Italian Art Art from Italy during the 1500’s is further categorized into the high Renaissance and late Renaissance. High Renaissance was comparatively short and was dominated by artists such as Leonardo, Michelangelo, and Raphael. Late Renaissance comprised of art composed from an estimated period of 1527 to 1600. Art made from this era has been highly referred to artists who used mannerism. Mannerism is the artistic technique employed and educated at an art academic facility called mannerism as well. High Renaissance was looked up as high because art from this era stood for culmination. Timid artistic journeying of Proto-renaissance blossomed in the course of Sixteenth-century Italian Art.

Tuesday, October 29, 2019

Employment Law College Case Study Example | Topics and Well Written Essays - 500 words

Employment Law College - Case Study Example Mary has the behavioral control wherein the facts are shown because Little Lamb Company has the right to direct and even control Mary for doing the task wherein the instructions were given by Little Lamb to Mary such as requiring her to use the company materials including the equipment while adhering to the schedules of company work. Mary is subject to the instructions of the company such as when, where, and absolutely how to work wherein this is a proof that Mary is really the common law employee rather than independent contractor because Mary is not using her own methods. As the common-law employee, the training with regards to the company, financial control and the extent for Mary has the unreimbursed company expenses and the independent contractors are said to be more likely to be able to reimburse the said business expenses. The fixed costs that are ongoing are said to be incurred not considering whether the said work is performed currently classified as specifically important. In defining the contract of employment, i

Sunday, October 27, 2019

Heterocycles: Types and Biosynthesis

Heterocycles: Types and Biosynthesis Heterocycles1 are one of the major classes of organic compounds. They are cyclic compounds containing one or more heteroatom (oxygen, nitrogen, sulphur etc.). These compounds are of biological and industrial importance. Many materials that are essential to life include a heterocyclic moiety; examples of these are: amino acids, nucleic acids, pigments, vitamins, antibiotics and many more. Heterocycles are part of our everyday life and are present in: drugs, dyes, pesticides and plastics.2, 3 Most common heterocycles are five or six membered ring; examples of these are pyridine, pyrrole, furan and thiophene (Figure 1). It is also possible to find two or more of them fused together to give even more complex structures.4 Figure 1: Common heterocyclic structures Many heterocyclic compounds are biosynthesised by plants and animals and hence have biological activity. These include as the haem group in the blood, and the chlorophylls ,essential for photosynthesis, both of these are essential to life.5 Examples of heterocycles used in the pharmaceutical industry include the pyridine based anti-AIDS-virus drug Nevirapine6, or the vasodilator Nicorandil for the treatment of angina (Figure 2).7 Figure 2: Example of heterocyclic drugs Pyrimidines are an important class of heterocycles that are essential to life and biologically and pharmacologically active. Cytosine, thiamine, uracil, adenine, guanine are the nitrogen bases that are present in both DNA and RNA (Figure 3); derivatives of these have been used to form the core of drug molecules, due to their ability to selectively interact with the human body.3, 7 Figure 3: Pyrimidines 2. Synthesis of heterocycles There are various traditional pathways leading to high yielding heterocyclic synthesis. Two of the most common are: Fischer-indole1, 8 synthesis and a Hantzsch synthesis to obtain the pyridines. Fisher-indole synthesis (Scheme 1) has been the most important method for the preparation of substituted indoles. It involves the formation of an imine 1.3 from a hydrazine 1.1 and a ketone 1.2. This will then tautomerise to give a enamine 1.4 that will subsequently undergo a [3,3] Cope rearrangement and form a di-imine 1.5, that will then aromatise. The aromatised amine 1.6 will undergo further intramolecular cyclisation to give the indoline 1.7 which will also aromatise to give the second ring system of the indole 1.8.4, 7 Scheme 1: Fischer-indole synthesis of indoles The Hantzsch1, 8 synthesis (Scheme 2), is a three component reaction, which firstly involves an aldol condensation of a diketone 2.1 with acetone 2.2. This is then followed by a conjugate addition of another equivalent of a diketone 2.1 to give a tetraketone 2.4. By adding ammonia it will lead to the formation of an imine and enamine component 2.5, which will subsequently react with sodium nitrate and acetic acid to aromatise to give pyridine 2.6.9 Scheme 2: Hantzsch synthesis of pyridines These two synthetical techniques have been greatly utilised however they have their downsides; which range from the need for high temperatures, large amounts of stoichiometric reagents, as well as the poor accessibility of the starting materials. This has therefore driven research for the discovery of new methodologies for an efficient route for the synthesis of heterocycles and their derivatives. A wide range of new heterocyclic synthetic routes using metal cross coupling reactions have arisen in particular utilising palladium as catalyst10, examples which are considered in the section below. 2.1. Synthesis of indole heterocycles using catalysis A palladium catalysed Fisher indole synthesis has been discovered by Wagaw et. al.. It involves the cross coupling of an aryl bromide and a hydrazone. This palladium catalysed reaction has proven to be very versatile in respect to the functionality of both the reagents used. The addition of the p-toluenesulfonic acid monohydrate hydrolyses imine 3.3 therefore liberating the hydrazine which will subsequently react with a ketone to give a hydrazone. This will then undergo standard Fischer-indole process to produce 3.4 (Scheme 3).11 Scheme 3: Palladium catalysed Fischer-indole synthesis 2.1.1. Palladium catalysed reactions Palladium catalysed reactions have been regularly used in both academic and industrial synthetic chemistry laboratories as an important method for the formation of carbon-carbon and carbon-heteroatom bonds. These have been heavily applied in the synthesis of pharmaceutically and biologically important molecules.1, 12 Many palladium catalysed reactions go through a similar catalytic cycle. The catalytic species can be formed in situ by using a palladium source such as Pd(PPh3)2Cl2 or Pd(OAc)2 with the addition of an appropriate ligand. By choosing the correct ligand this can improve two steps in the catalytic cycle; oxidative addition and reductive elimination.13 A common feature of these catalytic process (Scheme 4) is the formation of aryl/alkyl Pd(II) intermediates which will then be functionalised to form C-C or C-Heteroatom bonds that are cleaved off from the metal centre.14 Most of the Pd catalysed reactions undergo the same basic catalytic cycle involving; oxidative addition, transmetallation and reductive elimination. Scheme 4: Palladium catalytic cycle 2.1.2. Palladium catalysed cross coupling reactions Below in Table 1 are described some of the most common palladium catalysed reactions.15-18 Table 1: Palladium catalysed reactions Name of Reaction Suzuki Stille Negishi Hiyama Sonogashira Heck Buckwald-Hartwig Catalyst Pd(0) Pd(0) Pd(0) Pd(0) Pd(0), Cu(I) Pd(0) Pd(0) Base Yes No No Yes Yes Yes Yes Reagent 1 Reagent 2 R= EWG (eg. NO2, CN, COOR) Product 3. Recent examples of heterocyclic synthesis There are various recent examples of interesting heterocycles synthesis. Large amounts of research covering aspects of C-H activation, atom economy improvements and efficiency with the use of different solvents has been carried out to improve the conditions of the synthesis. An interesting class of heterocyclic moiety is pyrimidines due to their desirable biological activity. Over recent years the pyrimidine system (Figure 4) has been shown to be an important pharmacophore.19 Figure 4: Pyrimidine moiety Pyrimidines are very prevalent in nature; they are the precursors for the nucleoside bases of both DNA and RNA (Figure 3) and are also found in many more natural products such as vitamins and antibiotics. Examples, of this class of heterocycles, are shown below in Figure 5.19 Figure 5: Natural products containing pyrimidine moiety As a result of this long-lasting interest in the pyrimidine moiety as well as in its derivatives in the use as potential drug targets, the synthesis of this heterocyclic ring has been expansively researched.15 Good yielding strategies have been developed primarily on the basis of nitrogen-carbon-nitrogen condensation reactions. An example of this is the Pinner addition (Scheme 5) of guanidines 5.2 and amidine salts to 1,3-diketones 5.1 or their derivatives.20 Scheme 5: Pinner addition for the synthesis of pyrimidines 3.1. Synthesis of ÃŽ ²-Enaminones: an entry into pyrimidines Gayon et. al.21 have demonstrated highly stereoselective synthesis of ÃŽ ²-enaminones via based catalysed rearrangement of propargylic hydroxylamines. ÃŽ ²-Enaminones are versatile compounds that have been used for their pharmacological activity, as building blocks for natural product synthesis and heterocyclic synthesis. The initial discovery showed that propargylic hydroxylamine 6.1 underwent rearrangement to give the Cbz-protected enaminone 6.2 as a single (Z) diastereomer (Scheme 6) which could then be used for the synthesis of heterocyclic compounds such as pyrimidines. Scheme 6: Base catalysed rearrangement reaction to afford ÃŽ ²-enaminones The reaction mechanism (Scheme 7) starts from the deprotonated aminol 7.2 that is easily formed; this is due to the association of the hydroxyl anions present in solution with the propargylic hydroxylamine 7.1. With the deprotonation takes place at the propargylic position an imine 7.3 is formed this is also because of the elimination of hydroxyl anions which are triggered by the deprotonation itself. Hydroxyl anions add to the imine which will eventually for the allenol 7.4. This can then undergo keto-enol tautomerisation to produce the deprotonated enaminone 7.5. The last step involves proton exchange between another molecule of propargylic hydroxylamine 7.1 and the anionic deprotonated enaminone 7.5 to give the product and another molecule of aminol 7.6. Scheme 7: Mechanism for rearrangement These enaminones proved to be an interesting building block for the synthesis of heterocyclic compounds such as pyrimidines. The presence of a nucleophilic nitrogen atom, a double bond and an electrophilic carbonyl provided an different cyclocondensation process to simple Pinner addition on the basis of the addition of an electrophile/nucleophile partner; such as a carboxamide. Scheme 8: Propargylic hydroxylamine to pyrimidines The presence of the nitrogen atom on the enaminone 6.2 is advantageous for an alternative synthetic route for the synthesis of functionalised pyrimidines (Scheme 8) from readily commercially available and inexpensive carboxamides that can give easier access to pyrimidines. 3.2. Synthesis of Pyrazine Heterocycles and their Derivatives Pyridazines have been considered one of the ‘most drugable’ heteroaromatic rings for medicinal purposes.22 Its analogues have proved to be good starting points for developing drugs for various molecular targets and have demonstrated biological activity in many key areas such as obesity, neurodegenerative diseases, inflammatory pain and many more.22 Abed et al. have recently elaborated a synthesis of novel fused pyridazines by carrying out a diaza-Wittig reaction on 1,3-diketones (Scheme 9).20 Scheme 9: Synthesis of pyrazine heterocycles The work was divided in two parts; the first was the development of a convenient strategy to obtain versatile pyridazines containing an ester group at position 6 as a point of divergence. The latter steps involved the synthesis of pyridazines 9.4 with a ketone group at position 6. Towards this aim, different methods of cyclization techniques were applied which led to the formation of previously not known biheterocyclic compounds. This novel methodology provided an attractive synthesis for fused pyridazines derivatives (9.5, 9.6, 9.7, 9.8).20 The synthesis of functionalised pyridazines 10.4 (Scheme 10) proceeded via a diaza-Wittig reaction (10.3 to 10.4, step b.) affording a convenient and safer method for the synthesis of nitrogen heterocycles. Scheme 10: Synthesis of pyridazines 3.3. Direct imine acylation for heterocyclic synthesis Much attention has been focussed on the synthesis of diverse heterocyclic structure to advance the discovery of novel lead compounds for pharmaceutical discovery. A particularly useful approach is the formation of N-acyliminium ions from the acylation of imines with acid halides and anhydrides. This is a well-known reaction but very little work has previously been carried out to show the full potential of these ring closure reactions.23 Unsworth et. al. has provided a neat ring closing reaction (Scheme 11) by using propylphosphonic acid anhydride 11.3 (T3P) and NEt(iPr)2 for the coupling of aliphatic acids 11.2 (containing oxygen, nitrogen and sulphur nucleophiles) to imines 11.1. This will generate N-acyliminium ions 11.4 that can easily be trapped intramolecularly by the nucleophilic substituents that are present on the aliphatic acid fragment to form 11.5. Scheme 11: Ring closing reaction for heterocyclic synthesis This methodology has been used by Unsworth for the synthesis of the natural product evodiamine (Figure 6).24 Figure 6: Synthesis of evodiamine 4. Domino reactions A process that involves two or more bond-forming transformations that can take place under the same reaction conditions without additional reagents and/or catalysts, are considered to be domino/tandem reaction.25 In the past decades, synthesis of heterocyclic compounds through new domino reactions has attracted many researches and is still an expanding area.26 The idea of building simple and complex heterocycles starting from very easy and reasonable building blocks using a ‘single pot’ reaction with consecutive transformation taking place, is an attractive tool for synthetic chemists, especially if the synthesis can be used to create multiple stereogenic centres.26, 27 This ‘one pot’ strategy has many advantages; reduction of solvent, waste production, reaction time and atom economy28, all of which are important for developing a more sustainable chemistry. One single reaction can potentially convert an inexpensive material to a highly complex, biologically active heterocyclic molecule.26, 29 For many years the research groups of Valotti and Arcadi have focussed their interests in developing a new synthetic route for the construction of nitrogen-containing heterocycles starting from alkyne derivatives.30 They have focused most of their attention on the synthesis of nitrogen containing heterocycles by the condensation of ketoalkynes with ammonia.30 Examples of these are shown below in Scheme 12 and show the 5-exo-dig cyclisation reactions of 4-pentynones 12.1 to synthesise polysubstituted and joined pyrrole derivatives 12.2, Ketoalkyne moiety 12.5 in an aromatic framework would allow a 6-endo-dig cyclisation of 5-acetyl-4-alkynylthiazoles 12.6 and 2-acyl-3-alkynylindoles 12.7 to pyrido[3,4-c]thiazole and pyrido[3,4-b]indoles 12.8.31, 32 Scheme 12: Synthesis of pyrrole, pyridine and indole nitrogen containing heterocycles Another example of a tandem reaction for heterocyclic synthesis is the intermolecular 1,3-dipolar cycloaddition of nitrones for the formation of cyclic isooxazolidines ( Scheme 13). For example an interesting method has been developed for the generation of the cyclic isooxazolidines frameworks by using cheap and accessible starting material, such as Amaryllicaceae alkaloids, through a 1,2-prototropic shift of oximes. Scheme 13: Tandem reaction for cyclic isooxazolidines Wildman observed that the reaction of 6-hydroxybuphandidrine with hydroxylamine produced a cycloadduct; the reaction occurs by the formation of an intermediate oxime that then undergoes a subsequent 1,2-prototropic shift to give the nitrile oxide that then undergoes an intramolecular [1,3]-dipolar cycloaddition reaction. 5. Indoles In both nature and drug discovery, a common nitrogen containing heterocycle is indole and its derivatives. These naturally occurring molecules are present in a range of compounds (Figure 7) such as amino acids (tryptophan) and hormones (melatonin) and many others.33 Figure 7: Naturally occurring indoles As indoles are structural components of a large number of biologically active natural compounds, their synthesis and functionalization has been heavily researched, and is a crucial step in the preparation of many pharmaceutical compounds.33 Below, in Figure 8, are a couple of examples of indole containing pharmaceuticals and their applications; Sumatripan used for the treatment of migraine and Arbidol as an antiviral drug.34 Figure 8: Indole containing pharmaceutical compounds Another potential application for indoles is the possible use of indole derived nitrones as spin traps which can be employed as free radical probes for the identification of radicals in chemical and biological systems.35, 36 The pyrroline based 5,5-dimethyl-pyrroline N-oxide (DMPO) followed by the 5-carbamoyl-5-methyl-l-pyrroline N-oxide (AMPO) have often been used as nitrene spin traps in the past years (Figure 9).37 The use of spin trapping has gained attention in the recent years and it is currently being used in the investigation of reactive intermediates in the areas of fuel cell research, nanotechnology, catalysis, environmental remediation and photodynamic therapy using electron paramagnetic resonance (EPR).38 Figure 9: DMPO and AMPO spin traps The main disadvantages with many spin trap nitrones, for example DMPO, is the formation of secondary EPR signals; caused by the formation of other radical species caused by the instability by hydrolysis, decomposition and various other side reactions.37 Also, the slow reactivity of the superoxide radical anion to the nitrones and the short half-life of the spin adducts together, with slow rate of passive diffusion through the cell membran decreases their application in the human body as O2. – probes, unless further modifications can be carried out.38 Variants of the DMPO that contain indole moieties are 1,1,3-trimethyl-1H-isoindole-N-oxide (TMINO) and 1,1-dimethyl-3-(trifluoromethyl)-1H-isoindole-N-oxide(3-TF-TMINO) (Figure 10) which offer more stability to the oxygen radical adduct.37 Figure 10: Novel spin trap nitrones 6. Isoindolinone and Isoindoline Novel structures related to indoles such as isoindoline and isoindolinone compounds (Figure 11) are still relatively unexplored and have only begun to be explored over the past few years. Figure 11: Isoindoline and Isoindolinone Both of these structures have attracted a large amount of attention as pharmacophores due to their potential physiological and chemotherapeutic activity. These bicyclic models moieties have found a large importance as intermediates in the synthesis of various dugs and natural products.39 The more stable isoindolinones in particular demonstrate fascinting biological properties40, 41 as part of biologically active natural products such as magallanesine as well as drug candidates such as pagoclone shown in Figure 12.42 Figure 12: Isoindolinones as drug candidates The biological activity of isoindolinones has been utilised for the preparation of drugs for treatments in a wide range of diseases (Figure 13) such as: diabetes treatment, anti-inflammatory, anti-hypertensive, antipsychotic agents, for the modulation of dopamine D receptor, inhibitors of amyloid protein aggregation for the treatment of Alzheimer, selective antagonist of Essential Thromobocythemia (ET) diseases related to the heart and the lungs, melanocortin subtype-4-receptor in the targeting of weight disorder and sexual dysfunction43 and as antileukemic agents.42, 44-46 Figure 13: Isoindolines as drug candidates There have been several methods employed traditionally for the synthesis of these compounds based on use of a wide range of transformation, such as Diels-Alder, Grignard reagents, reductions, Wittig reactions and photochemical reactions. An example of one of them follows in Scheme 14. Scheme 14: One pot synthesis of isoindolinones The traditional routes are usually complex and have proved to be very unsatisfactory due to the low yields and the expensive starting material.39 Most approaches do not provide a large compatibility with many functional groups and suffer from a lack of generality.38, 42 New approaches have arisen in the past decades involving palladium chemistry and lithiation procedure for the synthesis of substituted isoindolinones that have proved to be easier to handle. An example of this is shown below (Scheme 15).47 Scheme 15: Lithiation and substitution

Friday, October 25, 2019

Plagiarism and the Internet :: Cheating Education Essays

Plagiarism and the Internet The web influences peopleà °s lives relating to plagiarism and the law. In this paper I will discuss why plagiarism is increasing with time. Technology is becoming more prominent each day. Now, personal computers are seemingly a necessity in college dormitories. They are even being used routinely for nightly homework assignments for high school and even elementary school students. Moreover, the web is not only being used for research assignments, but also for game-playing, meeting new people, and quicker, easier communication. This increase in Internet usage is recognizable on a personal basis alone. As a high school freshman, the computer was not used nearly as much as it was as a high school senior. High school assignments were computer based, but in only four years, it seemed as if subject curriculums were being modified to incorporate more computer-based projects and activities to parallel the computerà °s increasing use in society. Although computer use is increasing in society, ethics are decreasing. As students are directed to use the web on a routine basis to complete assignments, many worth a substantial part of the courseà °s grade, it is nearly impossible to avoid a pop-up advertisement or a website that diverts the student from valuable information to lengthy papers covering nearly every conceivable topic. Even the most gifted students are tempted at times since society is moving at a fast pace, and people are attempting to complete as many tasks in the least amount of time possible. This pressure to complete numerous tasks in short periods of time promotes a cheating environment. People, students more specifically, want to do things as easily as possible. In addition, many students are not caught cheating, so they will make a habit of cheating time and time again. Even those that are caught cheating are not always reprimanded in the proper way. In fact, some students caught cheating are not even disciplined at all, as teachers are afraid to confront a student or deal with administrative issues. This is a fine example of how school systems are less ethical than in years prior. On a broader forum, society is becoming less and less ethical, not just school systems. There are an increasing number of television shows where experts will argue the ethics of a situation, simply because the law can be used to support either side. For example, there has been a great deal of commotion dealing with downloading music.

Thursday, October 24, 2019

Chaucers View

It is said that Geoffrey Chaucer was one of the greatest English writers of all times. With Chaucer's straight forward personality, it is not shocking that he would express his arguments or beliefs through his work. One main points he made apparent in his writing was corruption going on in the Catholic Church During Chaucer's time, indulgences were of great controversy and Chaucer, along with many other people, were against them. He took this time to voice his feelings about the situation and wrote one of his most famous works; The Canterbury Tales.The Canterbury Tales is a series of tales, told by pilgrims on their journey to the shrine of Saint Becket. Many thought that Chaucer was simply telling a story, but little did people know he was criticizing the Catholic Church. Chaucer wrote The Canterbury Tales in order to preach a sermon against the Seven Deadly Sins due to its corruption in the Catholic Church. Within The Canterbury Tales, Chaucer uses the tales of certain characters t o symbolize the Seven Deadly Sins and corruption. The fabliau, as it took new form under Chaucer's compelling interest in characterization, brought him up against problems of mortality that were to become basic in the developed Canterbury Tales† (Owen 226). He uses tales such as The Knight's Tale, The Miller's Tale, The Pardoner's Tale, The Reeve's Tale, and The Parson's Tale which was a sermon itself. Notice he uses characters such as the pardoner and parson; members of the clergy to show that sinning was taking place in a holy place like the Catholic Church. Chaucer makes sure that he displays all the Seven Deadly Sins in his tales and some tales represent more than one of the sins.The Seven Deadly Sins consist of Lust, Gluttony, Avarice, Sloth, Anger, Jealousy, and Pride. According to New Advent, Lust is the inordinate craving for, or indulgence of, the carnal pleasure which is experienced in the human organs of generation. Sloth is said to be the disinclination to labor or exertion. Gluttony means excessive indulgence. Avarice is the inordinate loves for riches. Anger is defined as the desire of vengeance. Jealousy is a sorrow which one entertains at another's well-being because of their view that one's own excellence is in consequence lessened.Lastly, Pride is the excessive love of one's own excellence (Delany). Everyone of these sins are used in the following tales. One of the first tales in The Canterbury Tales to symbolize the Seven Deadly Sins was The Knight's Tale. In The Knight's Tale, Duke Theseus of Athens, is on his way home from attacking Scythia. While he was there, he wins over a wife and what now is a sister-in-law; Emily. Along the way, Theseus runs into a group of crying women. They beg Theseus to take revenge on Creon, the King of Thebes, because he refuses to bury their husbands.The oldest women stated â€Å"Their bodies were dragged out onto the plain into a heap, and there, as we have learnt, they neither may have burial nor be b urnt, but he makes dogs devour them, in scorn† (28). Theseus decides to fight Creon, and beats him. After winning against Creon, he takes two of his men; Palamon and Arcite to be servants for his castle. The servants are thrown in the tower to work without ransom. Over time, they both fall in love with Emily after watching her through the tower window. One day Arcite is let go, but with the promise of never returning.Arcite is envious of Palamon being able to see Emily everyday. On the other hand, Palamon was envious of Arcite being able to form an army to get Emily back. Arcite comes back in disguise and Palamon escapes, they run into one another and decide to fight over Emily. Arcite wins the battle, but with complications that caused death. Emily ends up marrying Palamon in the end, â€Å"That is called matrimony, also marriage, by counsel of the Duke and all his peerage. And thus with every bliss and melody Palamon was espoused to Emily† (86). The sins associated wi th this tale are Lust, Anger, Sloth and Jealousy.Since the characters in the tale did wrong and committed these sins, they had consequences. When Arcite and Palamon both Lust over Emily, it makes tension among them and makes it harder on themselves because they have no way of showing her affection. When Creon refuses to bury the bodies of the husbands, that shows Sloth, because of this Creon and Duke Theseus fight. Jealousy shows when Arcite and Palamon envy one other for being able to see Emily, this leads to them being angry at each another which eventually leads to greater problems. Anger shows up when Arcite and Palamon fight over Emily, which ends up with Arcite dying.This shows that with sinning, comes consequences. The next tale that Chaucer uses to preach is The Miller's Tale. The Miller's Tale is the tale of a carpenter, his young wife and two students. To make money, John rents rooms in his house to a boy named Nicholas. Nicholas soon has his eye set on Alison. Another boy in town, Absalon also has his eye on Alison. The trouble begins when John leaves home on a trip. While John is out, Nicholas and Alison have an affair. Not much longer after the affair, Alison goes to church where she is hit on by Absalon. She shows no affection towards him because she is in love with Nicholas.Alison and Nicholas think of a plan to trick John so they can have more alone time. Nicholas convinces John that God is sending a flood. â€Å"Rain is to fall in torrents, such a scud it will be twice as bad as Noah's Flood. This world,' he said, ‘in just about an hour, Shall all be drowned, it's such a hideous shower, and all mankind, with total loss of life† (97). He says that God told him they should hang three large buckets from the ceiling to sleep in and when the water got high, they would cut the ropes. John believes him and goes along with the plan.John thinks his wife is in her bucket, but little does he know that she is with Nicholas. Later that night, Absalon comes to the window and asks Alison to give him a kiss Instead of her lips, she sticks her butt out the window. Angry, Absalon gets a hot brand to brand Alison, but Nicholas sticks his butt out. Absalon brands Nicolas and he yells out â€Å"Water. † John thinks the flood is here and cuts his rope. The whole town hears about the situation and makes fun of John. The two sins tied into this tale are Lust and Anger. Lust is shown when both Absalon and Nicholas lust over the young wife of John.Since Nicholas lusted over her, it caused them to have an affair and Absalon lusting over made him go to the bedroom window which caused more problems. Anger sets in when Alison sticks her butt out of the window instead of her lips, when Absalon realizes, he turns angry and gets the hot brand and ends up branding Nicholas instead. This makes Nicholas yell out and than John cuts the ropes and makes a mockery out of himself by the town. Chaucer did not stop at just one or two tales, he decided to take it even further and use The Pardoner's Tale to help further his voice.In the Pardoner's tale, he starts off by going on a rant about young Flemish people who spend their time drinking, gambling, and swearing. He than starts back to his story. Three rioters are drinking and talking about a friend who was killed earlier by a thing called Death, â€Å"Many and grisly were the oaths they swore, tearing Christ's blessed body to a shred; ‘if we can only catch him, Death is Dead† (251). Outraged about their friend dying, the men go on a hunt to find and kill Death. On their way, they run into an old man who tells them that they can find Death underneath an oak tree. Pleased, the men rush to the tree to only find gold.They plan to steal the gold, but wait until night. During the wait, they send one man to go get wine and bread. While he is gone, they plot to kill him in order to split the gold. The man who went to fetch the bread, and wine was also thinking sim ilarly. He poisons the other two's wine and heads back to the tree, but to only get killed when he arrived. Excited about the gold, they drink the dead man's poisoned wine and they soon die. He goes to end his story, but forgets he had pardons and relics in his bag and asks for contribution. There are both Avarice and Gluttony take place in the Pardoner's Tale.We see Avarice take place when they set their eyes on the gold, all men are eager to get all the gold and in the end, their greed kills them all. We also see Gluttony, it takes place when the pardoner starts off talking about the Flemish boys, we also see it when the men are drinking too much in the bar. Them drinking too much in the bar, lead to them making stupid plans to kill Death. In the end they end up dead because of greed and a little too much to drink. The Reeves Tale's is yet another tale used by Chaucer to preach. The Reeve's Tale is about a miller named Simpkin who likes to fight and enjoys wrestling.Most people do n't talk to him and he cheats his customers by robbing corn from them. He also â€Å"paddles† their flour cheap substances. When the manciple of a school gets sick, the miller takes the opportunity to cheat the school even more. Two students, Alan and John are sent to do it for the school so they will not be cheated. When they arrive at the mill, Alan and John tell Simpkin that they will watch the corn being ground so they are not cheated. Simpkin gets angry and he unties their horses. When they find out the horses are missing, they go looking for them, giving Simpkin time to steal flour from them.He later has his wife bake a cake with it. Having wasted the whole day, Alan and John decide to stay the night at Simpkin's house Alan sneaks and has intercourse with Simpkin's daughter. John does the same with Simpkin's wife. He does this by moving the cradle to her bed to his so she will climb in with him. When Alan goes to bed he mistakes the cradle and goes into bed with Simpkin . Thinking he is John, Alan tells Simpkin that he had intercourse with the miller's daughter. Enraged, Simpkin rises out of bed and punches Alan in the nose. Alan and John beat Simpkin up, then run away picking up the cake made of their robbed flour on the way out.In the Reeve's Tale, there are many sins. We see Avarice, Anger, and Pride. We see avarice when the miller robs all the corn and flour, which results in the boys sleeping with his daughter and wife. We see Anger when the boys find out about the miller robbing them and anger when the miller finds out about the boys sleeping with the women, which causes a fight. We also see pride when Alan brags about sleeping with the miller's daughter to which he thought was John, which caused the miller to throw the first punch. â€Å"Chaucer had in mind the other Tales, when he finally conducted the Parsons through his against the Vices they illustrate?To me the conclusion seems unavoidable that this division of the Parson's sermon is b ut the culmination of the frequently recurring motifs of the Seven Deadly Sins† (Tupper 117). The Parson splits his sermon up into the three parts. He speaks of contrition, he talks of confession and he goes into depth about each of the seven deadly sins. Throughout the tale, the Parson recites several passages from the Bible. Chaucer wrote The Canterbury Tales in order to preach a sermon against the Seven Deadly Sins due to its corruption in the Catholic Church.It is obvious that he used tales such as the Knight's tale, the Miller's Tale, the Pardoner's tale, the Reeve's tale and especially the Parson's tale to get his point across. Even though The Canterbury Tales was never finished by Chaucer, it was a strong enough work to make people ask questions and think about the corruption going in the Catholic Church. Works Cited Chaucer, Geoffery. The Canterbury Tales. New York: Penguin Classics, 1997. Delany, Joseph. †Anger. † The Catholic Encyclopedia. Vol. 1. New Yor k: Robert Appleton Company, 1907. 13 Mar. 2013 ;http://www. newadvant. org/cathen/01489a. htm;. Delany, Joseph. â€Å"Avarice. The Catholic Encyclopedia. Vol. 7. New York: Robert Appleton Company, 1907. 13 Mar. 2013 ;http://www. newadvant. org/cathen/02148b. htm;. Delany, Joseph. †Gluttony. † The Catholic Encyclopedia. Vol. 6. New York: Robert Appleton Company, 1909. 13 Mar. 2013 ;http://www. newadvant. org/cathen/02148a. htm;. Delany, Joseph. â€Å" Jealousy. † The Catholic Encyclopedia. Vol. 8. New York: Robert Appleton Company, 1910. 13 Mar. 2013 ;http://www. newadvant. org/cathen/08326b. htm;. Delany, Joseph. â€Å"Lust. † The Catholic Encyclopedia. Vol. 9. New York: Robert Appleton Company, 1910. 13 Mar. 2013 ;http://www. newadvant. rg/cathen/09438a. htm;. Delany, Joseph. â€Å"Pride. † The Catholic Encyclopedia. Vol. 12. New York: Robert Appleton Company, 1911. 13 Mar. 2013 ;http://www. newadvant. org/cathen/12405a. htm;. Delany, Joseph. †Å"Sloth. † The Catholic Encyclopedia. Vol. 14. New York: Robert Appleton Company, 1912. 13 Mar. 2013 ;http://www. newadvant. org/cathen/14057c. htm;. Owen, Charles A. Jr. â€Å"Mortality as a Comic Motif in the Canterbury Tales. †Ã‚  National Council of Teachers of English. 16. 4 (1955): 226-232. Print. Tupper, Fredrick Jr. â€Å"Chaucer and The Seven Deadly Sins. â€Å"Modern Language Association America. XXIX. 1 (1914): 117. Print.

Wednesday, October 23, 2019

Internation Finance Essay

What was Nick Leeson’s strategy to earn trading profits on derivatives? Leeson was trading derivatives contracts on the two exchanges that were, in some cases, of different types and, in some cases, in mismatched amounts. He was hoping making profits by selling put and call options on the same underlying financial instrument, the Nikkei 225 Index. 2) What went wrong that caused his strategy to fail? He thought as the Nikkei was already low that it could not plummeted lower but due to among other reason, an earthquake and the volatility of the market it went even lower, at that time nick was already â€Å"all in â€Å" and could not correct his position. Also at a certain point he had contracted a lot of futures without enough options to hedge his position which put him or in this case the bank money at high risks. 3) Why did Nick Leeson establish a bogus error account (88888) when a legitimate account already existed? He created this account to be able to perform is unauthorized trading and hide his lost from Barings as this account was not shown on the statements transmitted to London. 4) Why did Barings and its auditors not discover that the error account was used by Leeson for unauthorised trading? The error account had been presenting by Leeson as a customer account, that’s why his activities were unknown for quite a long time. 5) Why did none of the regulatory authorities in Singapore, Japan, and the United kingdom discover the true use of the error account? Fist of all because Nick Leeson was in charge of the back office, letting him he possible to hide easily what he wanted. Also as we said above this account was represented as a customer account and differently to each group. 6) Why was Barings Bank willing to transfer large cash sums to Barings Futures Singapore? As Leeson lost money, he had to pay those losses to SIMEX in the form of margin. By falsifying accounts and making various misrepresentations, he was able to secure funding from various companies within the Barings organization and from client accounts. For example, he claimed that he needed funds to make margin payments on behalf of BSS clients. Therefore Barings believed that they were not exposed to any looses as Leeson claimed that he was executing purchase orders on behalf of clients 7) Why did the attempt by the bank of England to organize a bailout for Barings fail? No one wanted to assume to take the additional risk concerning the additional looses that were not yet determined. 8) Suggest regulatory and management reforms that might prevent a future debacle of the type that bankrupted Barings. -Separate trading, accounting and settlement activities. -More employees supervision -Clear reporting line -Consolidation of the activities of every branch.